Perelomov et al . included the Coulomb interaction at larger internuclear distances.
2.
Exchange energy splittings are very elusive to calculate for molecular systems at large internuclear distances.
3.
The process is driven by dipolar coupling, and is therefore related to internuclear distances.
4.
They then form a complex . . . RX at a fairly large internuclear distance.
5.
As this intersection occurs at a great distance, the ionic character of the binding of these states near the equilibrium internuclear distance r is virtually unaffected.
6.
Diffraction occurs because the wavelength of electrons accelerated by a potential of a few thousand volts is of the same order of magnitude as internuclear distances in molecules.
7.
For the minimum potential curves corresponding to almost the same value of the internuclear distance ( r # 0.3 nm ), the energy difference measured experimentally is about 9940 cm.
8.
Although in the hydrogen molecule the exchange integral, Eq . ( 6 ), is negative, Heisenberg first suggested that it changes sign at some critical ratio of internuclear distance to mean radial extension of the atomic orbital.
9.
Potential curves of the states B and C intersect adiabatically with a potential curve correlated to + Cl at large internuclear distances : 7.1 nm experimentally and 7.19 nm and 6.3 nm States B and C merging at long-distance, intersect two successive potential curves correlated to + Cl.
10.
With reference to the potential curves of Figure 3, the potential curves of V ( + RX ) and V ( + RX ) intersect at a greater internuclear distance than 6s states in a region of strong interactions . in the states 6p [ 1 / 2 ] and 6p [ 3 / 2 ].
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